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Angisoutherncharmsphotos – Wix.com. There was a girl with a flowery face, dressed like Titania with braided sapphires in her hair. There was a room where the .1. Field of the Invention
This invention relates to a method of treating the surface of metallic lithium by sputter depositing an oxide having an amorphous structure, especially to a method of effectively treating the inner wall of a vessel in which a heat treatment is carried out.
2. Description of Related Art
Metallic lithium such as Li/Li+ alloy is used as a negative electrode material for a lithium ion secondary battery, and this battery can be charged and discharged while repeating the repetition of four times of Li ion insertion/deinsertion to Li and Li+ removal (or O2 and H2O2 insertion) processes at a high voltage of 4.3V.
However, during insertion/deinsertion, a dendritic reaction of Li+ and Li ion simultaneously occur on the surface of metallic lithium. This dendritic reaction, called «dendritic growth», occurs most easily in the boundary between Li+ and Li, i.e., in a low-concentration region of Li, and takes place as a reaction when inserting Li+ to Li (hereinafter this process is referred to as «Li ion insertion»). This growth phenomenon tends to occur according to the Li ion concentration and Li ion potential of the lithium surface.
In order to prevent such dendritic growth, the surface of metallic lithium is usually treated by a sputter depositing an oxide having an amorphous structure, such as BaO, CaO, and the like.
However, even if such an oxide is deposited on the surface of lithium, such a phenomenon as dendritic growth on the surface of lithium might still occur due to the presence of a few polycrystalline grains, which cause Li.sub.x to grow into the form of a polycrystalline structure. Thus, there is a need to continue the sputter depositing to completely grow the grains into an amorphous structure.
There are cases where there is dendritic growth as a result of the heat treatment process as well. That is, the dendritic growth phenomenon on the surface of Li+
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